WebFeb 21, 2005 · However, it is shown that [bmpy][N(Tf)(2)] is a better solvent for aromatic nitration than [bmpy][OTf]. This is due to the ease of formation of nitronium ion in the … Web(3 mM) in BMPy OTf at 37 °C for 2 h. (A) Structure of antibody conjugates with biotin and isotopomerase inhibitor (SN-38). (B) Blot analysis of Herceptin (Trastuzumab) modification with biotin azide in the presence of triphenylphosphine (red circle) or …
Phosphine-Mediated Three-Component Bioconjugation of Amino
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Unexpected Strong Acidity Enhancing the Effect in Protic Ionic
WebBefore the adaption of ionic liquids as solvents for the production of nitroaromatics, Dal and Lancaster studied two different ionic liquids, [bmpy][OTf] and [bmpy][N(Tf)2], and developed a regime by which the solvent may be recovered and reused. WebApr 15, 2024 · The phosphine-mediated urea-forming reaction was applied to a variety of amine- and azide-containing carbohydrates such as antibiotics, anti-tumor agent, and polysaccharide with corresponding... WebIn contrast, [BMPy][OTf] shifted the azeotrope towards the alcohol-rich region, yet it was not able to completely remove the azeotrope of this system at the studied concentrations. Data were modelled with the non-random, two-liquid (NRTL) model, which could describe the experimental data, with a root mean square deviation (RMSD) less than 0.015 ... mornington family lawyers